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First and second‐order Raman scattering of B 6 O
Author(s) -
Solozhenko Vladimir L.,
Kurakevych Oleksandr O.,
Bouvier Pierre
Publication year - 2009
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.2243
Subject(s) - raman spectroscopy , raman scattering , excitation , ultraviolet , line (geometry) , spectral line , excitation wavelength , order (exchange) , chemistry , wavelength , coherent anti stokes raman spectroscopy , infrared , x ray raman scattering , analytical chemistry (journal) , molecular physics , physics , optics , mathematics , geometry , finance , chromatography , quantum mechanics , astronomy , economics
First and second‐order Raman spectra of B 6 O and their dependence on the wavelength of the excitation line from IR (infrared) to deep UV (ultraviolet) has been studied. The first‐order Raman spectra contain 11 well‐resolved lines of the 12 expected modes 5 A 1g + 7 E g (space group R ‐3 m , point group D 3 d ). The second‐order Raman spectra contains eight lines that are resolved only in the case of the 244‐nm excitation line. Copyright © 2009 John Wiley & Sons, Ltd.