Raman spectroscopic study of the uranyl mineral metauranospinite Ca[(UO 2 )(AsO 4 )] 2 ·8H 2 O | Zendy

Čejka Jiří | Zendy; Sejkora Jiří | Zendy; Frost Ray L. | Zendy; Keeffe Eloise C. | Zendy

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Raman spectroscopic study of the uranyl mineral metauranospinite Ca[(UO 2 )(AsO 4 )] 2 ·8H 2 O

Author(s) -

Čejka Jiří,

Sejkora Jiří,

Frost Ray L.,

Keeffe Eloise C.

Publication year - 2009

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.2242

Subject(s) - uranyl , raman spectroscopy , chemistry , infrared spectroscopy , infrared , hydrogen bond , bond length , molecule , analytical chemistry (journal) , spectral line , crystallography , crystal structure , ion , physics , chromatography , astronomy , optics , organic chemistry

Raman spectra of metauranospinite Ca[(UO 2 )(AsO 4 )] 2 ·8H 2 O complemented with infrared spectra were studied. Observed bands were assigned to the stretching and bending vibrations of (UO 2 ) 2+ and (AsO 4 ) 3− units and of water molecules. UO bond lengths in uranyl and OH···O hydrogen bond lengths were calculated from the Raman and infrared spectra. Copyright © 2009 John Wiley & Sons, Ltd.

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