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FT‐Raman investigation of human dental enamel surfaces
Author(s) -
Mihály Judith,
Gombás Veronika,
Afishah Alias,
Mink János
Publication year - 2009
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.2194
Subject(s) - enamel paint , raman spectroscopy , human tooth , fourier transform infrared spectroscopy , tooth enamel , materials science , chemistry , fourier transform , dental enamel , analytical chemistry (journal) , composite material , optics , chromatography , mathematics , mathematical analysis , physics
FT‐Raman spectra of human enamel surfaces from sound, affected (with 1 cavity) and highly affected (with at least 3 cavities) tooth samples were analyzed by principal component analysis (PCA). Major differences between the unaffected and affected tooth samples seem to arise from the structural changes along the c ‐axis of hydroxyapatite, the chief crystalline component of human dental enamel. Based on Fisher index calculations, the most discriminative value was obtained for the intensity of the only Raman active ν 2 PO 4 3− (E 1 ) symmetric deformation mode at 428 cm −1 . Moreover, these changes can be observed through the whole tooth enamel surface, establishing a predisposition to caries correlated to chemical and structural composition of tooth enamel. No spectral changes regarding the CO 3 2− substitution were detected by both nondestructive FT‐Raman and FTIR (Fourier transform infrared) spectroscopy of the powdered teeth samples. Copyright © 2009 John Wiley & Sons, Ltd.