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Concentration‐dependent Raman study of noncoincidence effect in the NH 2 bending and CO stretching modes of HCONH 2 in the binary mixture (HCONH 2 + CH 3 OH)
Author(s) -
Ojha Animesh K.,
Srivastava Sunil K.,
Asthana B. P.,
Singh Ranjan K.
Publication year - 2007
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1618
Subject(s) - raman spectroscopy , chemistry , bending , anisotropy , isotropy , binary number , hydrogen bond , analytical chemistry (journal) , mole fraction , thermodynamics , optics , molecule , physics , organic chemistry , arithmetic , mathematics
The isotropic and anisotropic parts of the Raman spectra of NH 2 bending and ν(CO) stretching modes of HCONH 2 in a hydrogen‐bonding solvent, methanol, at different concentrations have been analyzed carefully in order to study the noncoincidence effect (NCE). In neat HCONH 2 , the experimentally measured values of noncoincidence Δν nc are ∼11 and ∼18 cm −1 for the NH 2 bending and ν(CO) stretching modes, which reduce to 0.45 and 1.14 cm −1 , respectively at the concentration of HCONH 2 in mole fraction, χ m = 0.1. The experimental results have been explained on the basis of two models, namely, the microscopic prediction of Logan and the macroscopic model of Mirone and Fini. The relative success of the two models in explaining the experimental data for both the modes have been discussed. It has been observed that in case of the ν(CO) stretching vibrational mode the Logan model can reproduce the experimental data rather precisely, whereas in the case of the NH 2 bending mode, Mirone and Fini model yields more accurate results. Copyright © 2006 John Wiley & Sons, Ltd.