Application of chemometric methods in Raman spectroscopic studies of molten salt system containing MgCl 2 ‐KCl: Experimental evidence for existence of Mg 2 Cl       7    3−     dimer and its Raman spectrum | Zendy

Dai Sheng | Zendy; Begun G. M. | Zendy; Young J. P. | Zendy; Mamantov G. | Zendy

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Application of chemometric methods in Raman spectroscopic studies of molten salt system containing MgCl 2 ‐KCl: Experimental evidence for existence of Mg 2 Cl 7 3− dimer and its Raman spectrum

Author(s) -

Dai Sheng,

Begun G. M.,

Young J. P.,

Mamantov G.

Publication year - 1995

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250261002

Subject(s) - raman spectroscopy , molten salt , dimer , chemistry , salt (chemistry) , analytical chemistry (journal) , spectral line , inorganic chemistry , chromatography , organic chemistry , optics , physics , astronomy

Investigation of the Raman spectra of the molten MgCl 2 ‐KCl system by the use of factor analysis indicates that the melt is a two‐component system involving equilibrium between MgCl 4 2−and Mg 2 Cl 7 3− . The pure Raman spectra corresponding to these two species are recovered from the broad features via a self‐modeling method.

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