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Vibrational spectra of tris(methylammonium) cyclotriphosphate
Author(s) -
George Bini Lizbeth,
Joe I. Hubert,
Aruldhas G.
Publication year - 1992
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250230708
Subject(s) - raman spectroscopy , chemistry , ring (chemistry) , ion , hydrogen bond , tris , spectral line , infrared spectroscopy , crystallography , analytical chemistry (journal) , molecule , organic chemistry , physics , biochemistry , astronomy , optics
IR and Raman spectra of (CH 3 NH 3 ) 3 P 3 O 9 were recorded and analysed. The vibrational bands due to P 3 O 9 3−and (CH 3 NH 3 ) + groups are identified. From the spectral analysis, it is inferred that the P 3 O 9 3−ion has a ring structure in the compound. Hydrogen bonds of moderate strength are observed between the external oxygen atoms of P 3 O 9 3−and NH 3 + groups.