Resonance Raman and far‐infrared studies of  n ‐Bu 4 NI 3  and  n ‐Bu 4 NBr 3 | Zendy

Zambounis J. S. | Zendy; Kamitsos E. I. | Zendy; Patsis A. P. | Zendy; Papavassiliou G. C. | Zendy

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Resonance Raman and far‐infrared studies of n ‐Bu 4 NI 3 and n ‐Bu 4 NBr 3

Author(s) -

Zambounis J. S.,

Kamitsos E. I.,

Patsis A. P.,

Papavassiliou G. C.

Publication year - 1992

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250230204

Subject(s) - raman spectroscopy , far infrared , infrared , resonance (particle physics) , chemistry , ion , excitation , line (geometry) , analytical chemistry (journal) , spectral line , infrared spectroscopy , symmetry (geometry) , nuclear magnetic resonance , physics , atomic physics , optics , mathematics , geometry , organic chemistry , quantum mechanics , astronomy , chromatography

The resonance Raman and far‐infrared spectra of n ‐Bu 4 NI 3 show the coexistence of symmetrical ( C 2ν ) and unsymmetrical ( C s ) I 3 − species, which are clearly distinguished by varying the wavelength of the excitation line. Only a slight deviation from D ∞ h symmetry has been deduced for the Br 3 − ions in n ‐Bu 4 NB 3 .

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