CARS vibration‐rotation  Q ‐branch spectrum of hydrogen chloride | Zendy

Edwards H. G. M. | Zendy; Greenhalgh D. A. | Zendy; Long D. A. | Zendy; Sherwood G. | Zendy

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CARS vibration‐rotation Q ‐branch spectrum of hydrogen chloride

Author(s) -

Edwards H. G. M.,

Greenhalgh D. A.,

Long D. A.,

Sherwood G.

Publication year - 1991

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250220808

Subject(s) - bar (unit) , vibration , rotation (mathematics) , raman spectroscopy , spectrum (functional analysis) , chemistry , hydrogen chloride , range (aeronautics) , atomic physics , analytical chemistry (journal) , hydrogen , rotational spectrum , spectral line , value (mathematics) , nuclear magnetic resonance , physics , materials science , rotational spectroscopy , mathematics , geometry , optics , inorganic chemistry , acoustics , composite material , quantum mechanics , organic chemistry , statistics , meteorology

The self‐broadening of the Q ‐branch vibration‐rotational lines in the CARS spectrum of HCl was studied over the pressure range 0.002‐1.000 bar and the temperature range 298‐1048 K. The broadening coefficients, σ p , are dependent on J at 298 and 550 K but are independent of J at higher temperatures; the σ p value of 1048 K is only about 25% of its value for J max at 298 K.

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