Vibrational spectra of trifluoromethylsulphenyl cyanide, CF 3 SCN | Zendy

Altabef A. Ben | Zendy; Cutin E. H. | Zendy; Védova C. O. Della | Zendy

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Vibrational spectra of trifluoromethylsulphenyl cyanide, CF 3 SCN

Author(s) -

Altabef A. Ben,

Cutin E. H.,

Védova C. O. Della

Publication year - 1991

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250220511

Subject(s) - raman spectroscopy , chemistry , cyanide , valence (chemistry) , infrared spectroscopy , infrared , spectral line , force constant , vibrational spectrum , computational chemistry , symmetry (geometry) , analytical chemistry (journal) , molecular physics , inorganic chemistry , molecule , organic chemistry , physics , optics , geometry , mathematics , astronomy

The infrared spectra of trifluoromethylsulphenyl cyanide, CF 3 SCN, in the vapour phase and the Raman spectrum of the liquid were obtained and interpreted in terms of C s symmetry. Assignment of 14 of the 15 fundamental vibrations is carried out. The valence force constants were calculated by a stepwise coupling method for the A ′ species. These values compare favourably with results from previous calculations on related compounds.

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