Raman and infrared spectra of the FeCl       6    3−     anion: Comparison of MCl 4  and MCl 6  vibrational frequencies | Zendy

Shamir Jacob | Zendy

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Raman and infrared spectra of the FeCl 6 3− anion: Comparison of MCl 4 and MCl 6 vibrational frequencies

Author(s) -

Shamir Jacob

Publication year - 1991

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250220209

Subject(s) - raman spectroscopy , infrared , ion , chemistry , infrared spectroscopy , analytical chemistry (journal) , spectral line , molecular vibration , bending , materials science , physics , optics , organic chemistry , astronomy , composite material

Raman and infrared spectra, including two newly reported Raman frequencies, of the hexachloroferrate anion FeCl 6 3−are presented. Comparison of the vibrational frequencies of MCl 4 and MCl 6 species indicates that the stretching frequencies increase with decrease in the coordination number, whereas the bending frequencies decrease. In addition, frequencies of the Cr–N vibrations of the hexacoordinated CrN 6 system of the Cr(NH 3 ) 6 3+cation are also reported.

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