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Raman and infrared study of crystalline methyltrichlorosilane
Author(s) -
Prystupa D. A.,
Anderson A.,
Lefebvre J. H.,
Torrie B. H.
Publication year - 1990
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250210708
Subject(s) - raman spectroscopy , infrared , crystal structure , infrared spectroscopy , molecule , crystal (programming language) , chemistry , phase (matter) , analytical chemistry (journal) , crystallography , materials science , organic chemistry , optics , physics , programming language , computer science
The Raman and infrared spectra between 30 and 3000 cm −1 of a new crystalline phase of methyltrichlorosilane, CH 3 SiCl 3 , at 20 K are reported. The spectra are consistent with a non‐centrosymmetric crystal structure with at least four molecules per unit cell. A glassy phase is also detected.