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Electronic, vibrational and resonance Raman spectra of the layered semiconducting compound NbS 3
Author(s) -
Sourisseau C.,
Cavagnat R.,
Fouassier M.,
Maraval P.
Publication year - 1990
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250210604
Subject(s) - raman spectroscopy , excited state , raman scattering , resonance (particle physics) , excitation , chemistry , infrared , spectral line , molecular physics , valence (chemistry) , atomic physics , analytical chemistry (journal) , nuclear magnetic resonance , optics , physics , organic chemistry , quantum mechanics , astronomy , chromatography
The electronic (900–250 nm), infrared and Raman (600–10 cm −1 ) spectra of polycrystalline samples of NbS 3 were investigated. A complete vibrational assignment is proposed and the band wavenumbers are compared for NbS 3 and the related ZrS 3 and NbS 2 Cl 2 . All the assignments have been checked by a complete valence force field calculation including intrachain, interchain and interlayer contributions. The potential energy distributions and mean square vibrational amplitudes so calculated and the values of force constants are in agreement with the two‐dimensional character of the lattice dynamics in NbS 3 . In addition, an extensive resonance Raman study has been performed using various exciting radiations in the visible (676.4–457.9 nm) and near‐UV regions (363.8 and 351.1 nm). The experimental unresolved Raman excitation profiles in the contour of two low‐energy electronic transitions (λ max ≈ 600 and 560 nm) exhibit interesting interference and exact resonance effects depending on the nature of the vibration. Taking account of multi‐state interference phenomena and inhomogeneous broadening effects, these profiles compare well with the computed ones on the assumption of weakly displaced oscillators. This allows conclusions to be drawn about the scattering mechanisms and the nature of the first electronic excited states.