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Raman and far‐infrared study of crystalline 1,1,1‐trichloroethane and 1,1,1‐trichloroethane‐ d 3
Author(s) -
Prystupa D. A.,
Anderson A.,
Torrie B. H.
Publication year - 1989
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250200907
Subject(s) - raman spectroscopy , infrared , chemistry , far infrared , lattice vibration , infrared spectroscopy , analytical chemistry (journal) , optics , organic chemistry , physics , condensed matter physics , phonon
Abstract The lattice vibrations of the low‐temperature phase of CH 3 CCl 3 and CD 3 CCl 3 have been observed by Raman and far‐infrared techniques. The results are compared with the predictions of group theory, and the peaks are assigned on the basic of their frequency shifts on deuteration. Low‐temperature Raman and far‐infrared spectra of the internal modes are also presented.