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Vibrational and electronic properties of tris(8‐hydroxyquinolinato)vanadium (III)
Author(s) -
Jubert A. H.,
Baró A. C. González,
Baran E. J.,
Sala O.
Publication year - 1989
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250200902
Subject(s) - raman spectroscopy , vanadium , chemistry , excitation , infrared , analytical chemistry (journal) , molecular vibration , infrared spectroscopy , photochemistry , molecule , inorganic chemistry , optics , organic chemistry , physics , quantum mechanics
A study of the electronic, infrared, Raman and pre‐resonace Raman spectra of the solid complex tris(8‐hydroxyquinolinato)vanadium(III) was performed. The excitation profiles of the vibrational modes that show preresonance on excitation with laser lines within the electronic bands in the visible region are reported and, on this basis and molecular orbital calculations, several vibrational and electronic absorption bands were assigned.