Raman spectroscopic study of phase transformation in single crystals of cadmium fluorosilicate hexahydrate | Zendy

Thakur Ganesh | Zendy; Verma A. L. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Raman spectroscopic study of phase transformation in single crystals of cadmium fluorosilicate hexahydrate

Author(s) -

Thakur Ganesh,

Verma A. L.

Publication year - 1989

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250200605

Subject(s) - raman spectroscopy , chemistry , ion , degenerate energy levels , phase transition , crystallography , cadmium , lattice vibration , phase (matter) , lattice (music) , analytical chemistry (journal) , phonon , condensed matter physics , optics , physics , organic chemistry , chromatography , quantum mechanics , acoustics

A detailed temperature‐dependent Raman study of oriented single crystals of CdSiF 6 · 6H 2 O down to 10 K was made in the region of internal vibrations and lattice modes. The frequency shifts, Iinewidths and intensities of some of the modes associated with the [Cd(OH 2 ) 6 ] 2+ and (SiF 6 ) 2− ions show abrupt changes at temperatures around 220 K and some doubly degenerate modes split into two components. These studies suggest that the system undergoes a structural phase transition at ca. 220 K.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research