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Resonance Raman and far‐infrared studies of charge‐transfer complexes of iodine
Author(s) -
Nour E. M.,
Chen L. H.,
Laane J.
Publication year - 1986
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250170608
Subject(s) - hexamethylenetetramine , chemistry , raman spectroscopy , adduct , phenazine , recrystallization (geology) , resonance raman spectroscopy , resonance (particle physics) , infrared , iodine , photochemistry , infrared spectroscopy , acridine , inorganic chemistry , organic chemistry , optics , physics , paleontology , particle physics , biology
The reactions of I 2 with phenazine (PH), acridine (AC) and hexamethylenetetramine (HMTA) have been investigated by resonance Raman and far‐infrared spectroscopy. The results indicate that the species (PH) 2 I + I 3 − , (AC) 2 I + I 3 − and (HMTA) 2 I + I 3 − are formed. However, the 1:1 adduct I 2 . PH is also produced and this can be obtained in relatively pure form by recrystallization.