Premium
Resonance Raman and far‐infrared studies of charge‐transfer complexes of iodine
Author(s) -
Nour E. M.,
Chen L. H.,
Laane J.
Publication year - 1986
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250170608
Subject(s) - hexamethylenetetramine , chemistry , raman spectroscopy , adduct , phenazine , recrystallization (geology) , resonance raman spectroscopy , resonance (particle physics) , infrared , iodine , photochemistry , infrared spectroscopy , acridine , inorganic chemistry , organic chemistry , optics , physics , paleontology , particle physics , biology
The reactions of I 2 with phenazine (PH), acridine (AC) and hexamethylenetetramine (HMTA) have been investigated by resonance Raman and far‐infrared spectroscopy. The results indicate that the species (PH) 2 I + I 3 − , (AC) 2 I + I 3 − and (HMTA) 2 I + I 3 − are formed. However, the 1:1 adduct I 2 . PH is also produced and this can be obtained in relatively pure form by recrystallization.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom