Pure rotational and vibration–rotational Raman spectra of  1 H 2 ,  1 H 2 H and  2 H 2 | Zendy

Edwards H. G. M. | Zendy; Farwell D. W. | Zendy; Gorvin A. C. | Zendy; Long D. A. | Zendy

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Pure rotational and vibration–rotational Raman spectra of 1 H 2 , 1 H 2 H and 2 H 2

Author(s) -

Edwards H. G. M.,

Farwell D. W.,

Gorvin A. C.,

Long D. A.

Publication year - 1986

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250170126

Subject(s) - raman spectroscopy , spectral line , bond length , analytical chemistry (journal) , atomic physics , chemistry , vibration , physics , nuclear magnetic resonance , crystallography , optics , quantum mechanics , chromatography , astronomy , crystal structure

The pure rotational ( S ‐branch) and vibration‐rotational ( Q ‐branch) Raman spectra of 1 H 2 , 1 H 2 H and 2 H 2 have been recorded photographically and analysed with a precision greater than that achieved in earlier investigations to produce values of the bond lengths. From a combination of these results and those obtained from the species 2 H 3 H, 1 H 3 H and 3 H 2 a mean value of the bond length in the equilibrium configuration of r e = 74.151±0.001 pm has been obtained.

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