Vibrational spectra and symmetry of 3,3,6,6‐tetramethylcyclohexa‐1,4‐diene | Zendy

Sjøgren Carl E. | Zendy; KlosterJensen Else | Zendy; Nielsen Claus J. | Zendy

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Vibrational spectra and symmetry of 3,3,6,6‐tetramethylcyclohexa‐1,4‐diene

Author(s) -

Sjøgren Carl E.,

KlosterJensen Else,

Nielsen Claus J.

Publication year - 1985

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250160614

Subject(s) - diene , planar , raman spectroscopy , symmetry (geometry) , spectral line , ring (chemistry) , vibration , chemistry , molecular physics , crystallography , materials science , physics , geometry , optics , mathematics , organic chemistry , quantum mechanics , computer science , natural rubber , computer graphics (images)

The vibrational spectra of 3,3,6,6‐tetramethylcyclohexa‐1,4‐diene as a vapour, a liquid, a crystalline solid and isolated in argon and nitrogen matrices at 13K have been recorded and interpreted in terms of a planar ring structure ( D 2h ). The fundamental modes of vibration have been assigned with the aid of a normal coordinate calculation and by comparison with the spectra of cyclohexa‐1,4‐diene.

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