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Vibrational spectra of chlorocyclopropane
Author(s) -
Green P. M.,
Wurrey C. J.,
Kalasinsky V. F.
Publication year - 1985
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250160309
Subject(s) - raman spectroscopy , infrared , chemistry , molecule , infrared spectroscopy , analytical chemistry (journal) , phase (matter) , spectral line , fourier transform , resolution (logic) , optics , physics , organic chemistry , quantum mechanics , astronomy , artificial intelligence , computer science
The gas‐phase Fourier transform infrared spectrum (4000‐400 cm −1 ) of chlorocyclopropane was recorded at a resolution of 0.5 cm −1 . For the first time, gas‐phase Raman and solid‐phase infrared and Raman spectra were obtained for this molecule. Liquid‐phase Raman and infrared spectra were also recorded and, on the basis of all the data, a complete assignment of the 21 normal modes of vibration of chlorocyclopropane was made. The proposed assignment is in excellent agreement with assignments for other substituted cyclopropanes and, in particular, other chlorine‐substituted cyclopropanes.