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Vibrational spectra of tribromoacetonitrile and [ 15 N] tribromoacetonitrile
Author(s) -
Arenas J. F.,
Marcos J. I.,
Suero M. I.
Publication year - 1984
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250150213
Subject(s) - cndo/2 , raman spectroscopy , spectral line , chemistry , depolarization , derivative (finance) , analytical chemistry (journal) , product (mathematics) , isotopic shift , physics , molecule , geometry , optics , mathematics , organic chemistry , medicine , astronomy , financial economics , economics , endocrinology
The IR and the low‐frequency Raman spectra of liquid tribromoacetonitrile and its 15 N isotopic derivative were recorded and assigned on the basis of isotopic shifts and depolarization ratios. The isotopic product rule has been successfully applied by assuming a CNDO optimized geometry.