Low‐temperature phase transition in 1,7‐dicarbaclosododecaborane ( meta ‐carborane) found by Raman and NMR methods | Zendy

Bukalov S. S. | Zendy; Leites L. A. | Zendy; Blumenfeld A. L. | Zendy; Fedin E. I. | Zendy

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Low‐temperature phase transition in 1,7‐dicarbaclosododecaborane ( meta ‐carborane) found by Raman and NMR methods

Author(s) -

Bukalov S. S.,

Leites L. A.,

Blumenfeld A. L.,

Fedin E. I.

Publication year - 1983

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250140315

Subject(s) - carborane , raman spectroscopy , plastic crystal , chemistry , phase (matter) , phase transition , crystallography , nuclear magnetic resonance , materials science , stereochemistry , organic chemistry , thermodynamics , physics , optics

A second phase transition in solid 1,7‐dicarbaclosododecaborane ( meta ‐carborane) in the vicinity of 165 K has been found by Raman and NMR T 1 studies. All three isomers of carborane are shown to exist in the solid in three crystal modifications, two of them plastic and the low temperature one ordered.

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