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Raman spectra of 1‐organosilatranes
Author(s) -
Imbenotte M.,
Palavit G.,
Legrand P.
Publication year - 1983
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250140302
Subject(s) - raman spectroscopy , chemistry , symmetry (geometry) , spectral line , crystallography , normal mode , analytical chemistry (journal) , stereochemistry , organic chemistry , physics , vibration , optics , geometry , mathematics , quantum mechanics , astronomy
The Raman spectra of five organosilatranes (R = H, CH 3 , (CH 2 ) 3 NH 2 , OC 2 H 5 and F) are reported. The normal modes of the cage are presented and the assignment of the Si‐N stretching mode is discussed on the basis of C 3 ν symmetry for the silatrane skeleton.