Determination of A 0  and D  k   for CD 3 I from the ν 4  Raman and IR bands | Zendy

Poulsen Carsten | Zendy; Brodersen Svend | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Determination of A 0 and D k for CD 3 I from the ν 4 Raman and IR bands

Author(s) -

Poulsen Carsten,

Brodersen Svend

Publication year - 1983

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250140204

Subject(s) - raman spectroscopy , analytical chemistry (journal) , infrared , chemistry , deuterium , high resolution , resolution (logic) , crystallography , nuclear magnetic resonance , physics , atomic physics , optics , geology , remote sensing , chromatography , artificial intelligence , computer science

The ν 4 Raman band of CD 3 I has been recorded at a resolution of 0.28 cm −1 . A weighted least‐squares analysis, including data from the ν 4 infrared band recorded by Peterson and Edwards, gave A 0 = 2.59608±0.00010 cm −1 and D K = (1.98±0.10)x10 −5 cm −1 in addition to values for ν, (Aζ) 4 , ΔA and ΔB The ν 4 state is essentially unperturbed. Using literature values for the α A constants, A e was calculated as 2.6200±0.0008 cm −1 , indicating a value of r e = 1.03192±0.00015 Å for the distance of the deuterium atoms from the figure axis.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research