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Raman spectra of pyridine N‐oxide complexes with Co(II) and Ni(II) perchlorates
Author(s) -
Arenas J. F.,
Marcos J. I.,
Otero J. C.
Publication year - 1983
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250140103
Subject(s) - raman spectroscopy , microcrystalline , chemistry , pyridine , ion , spectral line , oxide , crystallography , inorganic chemistry , analytical chemistry (journal) , medicinal chemistry , organic chemistry , physics , astronomy , optics
The complexes [(PyO) 6 Co](ClO 4 ) 2 and [(PyO) 6 Ni](ClO 4 ) 2 have been synthesized and their Raman spectra recorded from a microcrystalline powder. The experimental data agree with those previously calculated for the low frequency vibrations. General assignments of both spectra have been proposed on the basis of a group factor S 6 for both the cation and the anion.