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Raman and infrared studies on new anticancer inorganic ring systems. 1—hexaziridinocyclotriphosphazene N 3 P 3 (NC 2 H 4 ) 6
Author(s) -
Manfait Michel,
Alix Alain J. P.,
Labarre JeanFrançois,
Sournies François
Publication year - 1982
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250120302
Subject(s) - raman spectroscopy , valence (chemistry) , chemistry , solid state , infrared , ring (chemistry) , molecule , aqueous solution , infrared spectroscopy , crystallography , stereochemistry , physics , organic chemistry , optics
The Raman spectra of the new anticancer agent N 3 P 3 (NC 2 H 4 ) 6 (MYKO 63), in the solid state and in aqueous solution, and the infrared spectra of the molecule in the solid state, are reported for the first time. All the assignments are discussed in terms of the following vibrations framework (N 3 P 3 ); ligand (NC 2 H 4 ); and framework‐Iigand couplings (N endo2 PN exo2 ). The concept of group frequencies associated with local symmetrical valence coordinates is used extensively.