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A cation dependent low frequency vibrational band in aqueous solutions of 5′‐guanosine monophosphate
Author(s) -
Nielsen O. Faurskov,
Lund P.A.,
Petersen Steffen B.
Publication year - 1981
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250110613
Subject(s) - guanosine , aqueous solution , stacking , raman spectroscopy , chemistry , base (topology) , molecular vibration , raman scattering , guanosine monophosphate , low frequency , inorganic chemistry , crystallography , nucleotide , molecule , biochemistry , organic chemistry , optics , physics , mathematical analysis , mathematics , astronomy , gene
Abstract Low frequency Raman scattering of aqueous solutions of disodium‐5′‐guanosine monophosphate (GMP), dipotassium‐5′‐GMP, NaCl and KCl are studied by construction of a quantity R ( ν ). A band with a maximum at 115 cm −1 is assigned to a mode from mononucleotides, associated in a manner different from normal base stacking.

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