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Raman and IR spectra of tetrachloro phosphonium salts of some tetrachlorate (MCI 4 − ) anions
Author(s) -
Shamir Jacob,
van der Veken Benjamin J.,
Herman Medard A.,
Rafaeloff Rafael
Publication year - 1981
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250110312
Subject(s) - phosphonium , raman spectroscopy , chemistry , ionic bonding , aluminate , spectral line , inorganic chemistry , gallate , ion , materials science , nuclear chemistry , organic chemistry , physics , astronomy , cement , optics , metallurgy
Complete Raman and IR spectra were recorded for the tetrachloro phosphonium salts of tetrachloro‐aluminate, gallate, indate and ferrate. The spectra are interpreted on the basis of these complexes being of ionic structure of the general formula: PCL 4 + MCI 4 − . All the accordingly expected fundamentals have been observed and assigned.