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The association of surface enhanced raman scattering from cyanide at silver electrode surfaces with a stabilized oxide phase
Author(s) -
Mahoney Merrick R.,
Cooney Ralph P.
Publication year - 1981
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250110217
Subject(s) - cyanide , raman scattering , electrochemistry , electrode , raman spectroscopy , oxide , chemistry , inorganic chemistry , phase (matter) , materials science , optics , organic chemistry , physics
Surface enhanced Raman scattering from cyanide in the electrochemical system, Ag/0.1 M Na 2 SO 4 , 0.01 M KCN (pH∼11), appears to arise from a cyanide stabilized oxide film which is pH sensitive and reducible.
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