Resonance Raman spectrum of the transient dimethylsulfide dimer radical cation |(CH 3 ) 2 S| 2  +· | Zendy

Wilbrandt R. | Zendy; Jensen N. H. | Zendy; Pagsberg P. | Zendy; Sillesen A. H. | Zendy; Hansen K. B. | Zendy; Hester R. E. | Zendy

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Resonance Raman spectrum of the transient dimethylsulfide dimer radical cation |(CH 3 ) 2 S| 2 +·

Author(s) -

Wilbrandt R.,

Jensen N. H.,

Pagsberg P.,

Sillesen A. H.,

Hansen K. B.,

Hester R. E.

Publication year - 1981

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250110108

Subject(s) - raman spectroscopy , thioether , dimer , resonance (particle physics) , radical ion , chemistry , electron paramagnetic resonance , aqueous solution , analytical chemistry (journal) , photochemistry , infrared , nuclear magnetic resonance , ion , atomic physics , stereochemistry , physics , optics , organic chemistry

The resonance Raman spectrum of the transient thioether radical cation dimer complex |(CH 3 ) 2 S| 2 +· , generated by electron irradiation of an aqueous solution of dimethylsulfide and recorded by optical multichannel detection, is reported. Vibrational bands at 276 cm −1 and 139 cm −1 were detected and are assigned to the stretching mode of the quasi‐three‐electron SS bond and a δ(CSS) deformation mode, respectively.

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