Resonance‐Raman and electronic absorption spectra of O       3    −     ions in γ‐irradiated Cd(ClO 3 ) 2 | Zendy

Campelo L. C. | Zendy; Melo F. E. A. | Zendy; Mendes Filho J. | Zendy; Katiyar R. S. | Zendy; Vargas H. | Zendy

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Resonance‐Raman and electronic absorption spectra of O 3 − ions in γ‐irradiated Cd(ClO 3 ) 2

Author(s) -

Campelo L. C.,

Melo F. E. A.,

Mendes Filho J.,

Katiyar R. S.,

Vargas H.

Publication year - 1981

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250100107

Subject(s) - raman spectroscopy , ion , irradiation , resonance (particle physics) , chemistry , analytical chemistry (journal) , absorption spectroscopy , absorption (acoustics) , spectral line , raman scattering , wavelength , lattice (music) , atomic physics , materials science , optics , optoelectronics , physics , organic chemistry , chromatography , nuclear physics , acoustics , composite material , astronomy

Resonant vibrational Raman measurements of the O 3 −ion modes in γ‐irradiated Cd(ClO 3 ) 2 single crystals are reported. It is concluded that the O 3 −ions occupy only one non‐equivalent site in the host lattice, in accordance with the ESR measurements previously reported. Resonance enhancement of the fundamental mode and its overtones as a function of the exciting wavelength is also investigated. The activation energy is determined by a simple direct calculation.

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