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A Raman spectroscopic study of complexes of thiocyanate at the silver electrode surface
Author(s) -
Gold Harvey S.,
Buck Richard P.
Publication year - 1979
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250080606
Subject(s) - raman spectroscopy , thiocyanate , chemistry , electrode , stoichiometry , aqueous solution , inorganic chemistry , electrode potential , surface enhanced raman spectroscopy , analytical chemistry (journal) , electrochemistry , raman scattering , organic chemistry , optics , physics
Raman spectra of thiocyanate at the surface of a silver electrode and in a series of aqueous test solutions were compared. The results indicate that spectral variations can be correlated with changes in bonding stoichiometry at the electrode surface as a function of potential.