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The pure rotational and vibration‐rotational Raman spectra of 1 H 3 H and 2 H 3 H
Author(s) -
Edwards H. G. M.,
Long D. A.,
Mansour H. R.,
Najm K. A. B.
Publication year - 1979
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250080507
Subject(s) - raman spectroscopy , spectral line , molecule , hydrogen , atomic physics , analytical chemistry (journal) , vibration , chemistry , rotational transition , nuclear magnetic resonance , physics , angular momentum , optics , quantum mechanics , organic chemistry , chromatography
Abstract The pure rotational and vibration‐rotational Raman spectra of the hydrogen species 1 H 3 H and 2 H 3 H have been recorded and analysed. The following rotational constants, vibration‐rotational constants and bond lengths were obtained:The r e values are compared with those of 1 H 2 , 1 H 2 H, 2 H 2 and 3 H 2 and a weighted mean r e value for the hydrogen molecule was calculated.