Determination by Raman spectroscopy of the solvation number of the chloride ion in liquid hydrogen chloride | Zendy

Desbat B. | Zendy; Huong P. V. | Zendy

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Determination by Raman spectroscopy of the solvation number of the chloride ion in liquid hydrogen chloride

Author(s) -

Desbat B.,

Huong P. V.

Publication year - 1979

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250080313

Subject(s) - chemistry , solvation , chloride , tetramethylammonium , raman spectroscopy , inorganic chemistry , hydrogen chloride , ion , molecule , solvation shell , organic chemistry , physics , optics

Solutions of various concentrations of tetramethylammonium chloride and trimethylammonium chloride in liquid hydrogen chloride have been examined by Raman spectroscopy and the solvation number of Cl − anions in these solutions determined. It was found for solutions up to 3 mol I −1 of (CH 3 ) 4 N + Cl − in liquid HCl, that the Cl − anions are solvated by six HCl molecules, while trimethylammonium chloride exists in the form of ion pairs solvated by five HCl molecules, (CH 3 ) 3 N + H ⃛Cl − , 5HCl.

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