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The totally symmetric rotation‐vibrational Raman bands of benzene
Author(s) -
Jensen Hans Birger,
Brodersen Svend
Publication year - 1979
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250080208
Subject(s) - raman spectroscopy , infrared , benzene , chemistry , rotation (mathematics) , analytical chemistry (journal) , resolution (logic) , hot band , crystallography , molecular vibration , optics , physics , geometry , organic chemistry , mathematics , artificial intelligence , computer science
The ν 1 and ν 2 Raman bands of gaseous C 6 H 6 were photographed with a resolution of 0.20–0.25 cm −1 . The J structure was resolved, but not the K structure. The analysis yielded several constants, primarily B 0 = 0.189751 ± 0.000025 cm −1 (standard error). This number differs significantly from the value obtained by Cabana et al. from the rotational structure of the ν 11 infrared band.