Premium
Etude par spectroscopie Raman Du Chlorure Tetraammine Platine(II) et Dérivé Deutérie
Author(s) -
Manfait M.,
Alix A. J. P.,
Bernard L.,
Theophanides T.
Publication year - 1978
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250070307
Subject(s) - chemistry , raman spectroscopy , platinum , solid state , aqueous solution , crystallography , analytical chemistry (journal) , stereochemistry , physics , organic chemistry , optics , catalysis
The Raman spectra of the platinum complex [Pt(NH 3 ) 4 ]Cl 2 and [Pt(ND 3 ) 4 ]Cl 2 in the solid state and in aqueous solution and of [Pt(NH 3 ) 4 ]Cl 2 ·H 2 O in the solid state have been obtained and discussed. All the ligand vibrations in the deformation and rocking regions have been studied and some show interesting changes on hydration. The polarization data and high quality spectra obtained in this study allow a more complete assignment of the vibrational modes of the complex.