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Raman spectra of halate ions as solid solutions in sodium chlorate and bromate lattices
Author(s) -
Fornari B.,
Mattei G.,
Mattioli L.,
Pagan M.
Publication year - 1978
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250070203
Subject(s) - raman spectroscopy , sodium chlorate , ion , chemistry , chlorate , bromate , solid solution , local symmetry , doping , inorganic chemistry , spectroscopy , analytical chemistry (journal) , materials science , optics , physics , optoelectronics , organic chemistry , quantum mechanics , chromatography
The fundamental vibrational modes of the halate ions as solid solutions in NaClO 3 and NaBrO 3 lattices have been studied by laser Raman spectroscopy, both at room and at low (80 K) temperature. The four predicted modes have all been observed and assigned for each halate ion. The local symmetry of the doping ions in the host lattices at both temperatures is discussed.