Raman spectra of gases. XXI —bis(trifluoromethyl)peroxide | Zendy

Durig J. R. | Zendy; Bucy W. E. | Zendy; Natter W. J. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Raman spectra of gases. XXI —bis(trifluoromethyl)peroxide

Author(s) -

Durig J. R.,

Bucy W. E.,

Natter W. J.

Publication year - 1977

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250060508

Subject(s) - raman spectroscopy , peroxide , chemistry , trifluoromethyl , infrared , internal rotation , infrared spectroscopy , analytical chemistry (journal) , gas phase , spectral line , phase (matter) , organic chemistry , alkyl , optics , physics , mechanical engineering , astronomy , engineering

The Raman spectra of gaseous and solid bis(trifluoromethyl)peroxide, (CF 3 ) 2 O 2 , have been recorded from 20 to 1300 cm −1 . The infrared spectrum of the solid has been investigated from 35 to 1300 cm −1 . The far infrared spectrum of the gaseous phase was recorded from 20 to 250 cm −1 . A reassignment of the low frequency fundamentals has been made. Both CF 3 torsional modes have been observed in the solid and at least one in the gaseous phase. The barrier to internal rotation of the CF 3 top has been calculated to have a value of 0.73 kcal mol −1 in the gaseous phase.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research