Etude Vibrationnelle par Spectrométrie Raman en Phase Vapeur du Benzène d 3 . Détermination des Constantes de Coriolis des Espéces  E ′ et  E ″ | Zendy

Chapput André | Zendy; Guy Fleury Bernard Roussel | Zendy

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Etude Vibrationnelle par Spectrométrie Raman en Phase Vapeur du Benzène d 3 . Détermination des Constantes de Coriolis des Espéces E ′ et E ″

Author(s) -

Chapput André,

Guy Fleury Bernard Roussel

Publication year - 1977

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250060403

Subject(s) - raman spectroscopy , chemistry , analytical chemistry (journal) , physics , symmetry (geometry) , gas phase , nuclear magnetic resonance , geometry , mathematics , optics , chromatography

The gas phase Raman spectrum of benzene d 3 has been recorded at medium resolution. The band contours of E ′ and E ″ degenerate species have been observed and their computer simulation has allowed the determination of the Coriolis constant values. Five fundamental bands of E ′ symmetry and two of E ″ symmetry have been computed. This analysis has given the values of ζ 6 , ζ 8 , ζ 9 , ζ 19 , ζ 20 ( E ′), ζ 10 , ζ 16 , ( E ″). ζ 18 ( E ″) has been calculated from the zeta sum rules.

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