Infrared and Raman spectra of CuSO 4 , 5H 2 O; CuSO 4 , 5D 2 O; and CuSeO 4 , 5H 2 O | Zendy

Berger J. | Zendy

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Infrared and Raman spectra of CuSO 4 , 5H 2 O; CuSO 4 , 5D 2 O; and CuSeO 4 , 5H 2 O

Author(s) -

Berger J.

Publication year - 1976

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.1250050202

Subject(s) - raman spectroscopy , chemistry , raman scattering , selenate , infrared , crystallography , analytical chemistry (journal) , infrared spectroscopy , copper , spectral line , molecular vibration , selenium , physics , optics , organic chemistry , astronomy

The Raman spectra of oriented single crystals of Copper (II) sulphate and selenate at 290 K and 150 K are reported and compared. Assignments are proposed for numerous internal modes of the crystals. Raman scattering tensors are calculated for the normal modes of (SO 4 ) 2− and (SeO 4 ) 2− and compared with experimental results. The structure and the part played by ligands (SO 4 ) 2− and (SeO 4 ) 2− in these crystals are stated precisely. The molecular complexes Cu(H 2 O) 4 and Cu(D 2 O) 4 are characterized by the assignment of their vibrational frequencies.

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