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Determination of A 0 for CH 3 D from the ν 4 Raman band
Author(s) -
Kattenberg H. W.,
Brodersen Svend
Publication year - 1976
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250040314
Subject(s) - raman spectroscopy , infrared , analytical chemistry (journal) , yield (engineering) , ground state , chemistry , materials science , physics , optics , atomic physics , chromatography , metallurgy
The ν 1 Raman band of CH 3 D has been analysed by means of ground state combination differences. The results are in good agreement with those obtained by Olson from perturbationallowed infrared transitions. The present work removes a previous discrepancy between infrared and Raman results, and shows that the Raman method may yield A 0 values with low systematic errors.