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A Raman spectroscopic investigation of the conformation of the cyclohexyl halides C 6 H 11 X (X = Cl, Br and I) in thiourea clathrates
Author(s) -
Allen A.,
Fawcett V.,
Long D. A.
Publication year - 1976
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250040310
Subject(s) - halide , raman spectroscopy , iodide , thiourea , clathrate hydrate , chemistry , bromide , crystallography , chloride , inorganic chemistry , hydrate , organic chemistry , physics , optics
The Raman spectra of the cyclohexyl halide‐thiourea clathrates have been investigated. It is found that whereas cyclohexyl chloride and bromide exist only in the axial conformation in the clathrate, cyclohexyl iodide exists in both the axial and equatorial conformations in the clathrate.