Premium
Raman spectrum of the addition compound of uranium and phosphorus pentachlorides (UCl 5 ,·PCl 5 ) and its structure
Author(s) -
Shamir Jacob,
Silberstein Atara
Publication year - 1974
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250020609
Subject(s) - raman spectroscopy , symmetry (geometry) , uranium , chemistry , ion , ionic bonding , crystal structure , phosphorus , crystallography , materials science , physics , organic chemistry , metallurgy , optics , mathematics , geometry
The Raman spectrum of the addition compound of PCl 5 · UCl 5 was recorded. In all, seven major lines were observed. The results were interpreted as supporting the ionic structure of PCl 4 +UCl 6 − , the cation having a T d symmetry and the anion an O h symmetry.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom