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The rotational and rotation‐vibrational Raman spectra of HCN and DCN
Author(s) -
Bendtsen Jørgen,
Edwards Howell G. M.
Publication year - 1974
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250020412
Subject(s) - raman spectroscopy , chemistry , infrared , rotational spectroscopy , rotation (mathematics) , hot band , infrared spectroscopy , microwave , spectral line , coherent anti stokes raman spectroscopy , molecular physics , analytical chemistry (journal) , molecular vibration , molecule , nuclear magnetic resonance , atomic physics , raman scattering , optics , physics , geometry , organic chemistry , mathematics , quantum mechanics , astronomy
The pure rotational and rotation‐vibrational Raman spectra of HCN and DCN have been photographed using a previously described instrument [7]. The molecular constants derived for HCN are in excellent agreement with those obtained from microwave and infrared spectroscopy. Especially, the measurements of the v 1 rotation‐vibrational Raman band have confirmed the hitherto indirectly obtained values for the molecular constants of the v1 vibrational state of HCN.