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Vibrational spectra of substituted platinum(IV) ammine complexes. I: [Pt (NH 3 ) 6 ] 4+ ; [Pt (NH 3 ) 5 X ] 3+ , X = Cl, Br; mer [Pt (NH 3 ) 3 Cl 3 ] + and [Pt(NH 3 )Cl 5 ] −
Author(s) -
Nolan M. J.,
James David W.
Publication year - 1973
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250010306
Subject(s) - raman spectroscopy , chemistry , platinum , infrared spectroscopy , solid state , spectral line , infrared , ion , analytical chemistry (journal) , crystallography , inorganic chemistry , physics , catalysis , organic chemistry , astronomy , optics , biochemistry , chromatography
The Raman and infrared spectra (4000–40 cm −1 ) have been recorded for the salts [Pt (NH 3 ) 6 ]Cl 4 , [Pt (NH 3 ) 5 X ] X 3 ( X = Cl, Br), mer [Pt (NH 3 ) 3 Cl 3 ]Cl and K [Pt (NH 3 )Cl 5 ], in the solid state. The results are primarily explicable on a point group model for the complex ion. For the monohalo and pentahalo derivatives solution Raman spectra were recorded. These indicated that solid state effects are more pronounced for the monohalo derivatives.