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Rotational structure of hyper‐Rayleigh scattering by linear molecules
Author(s) -
Bancewicz T.,
Ożgo Z.,
Kielich S.
Publication year - 1973
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250010205
Subject(s) - rayleigh scattering , linear molecular geometry , rotational partition function , angular momentum , rotational transition , molecule , rotation around a fixed axis , spectral line , atomic physics , raman scattering , scattering , molecular physics , physics , raman spectroscopy , chemistry , line (geometry) , computational physics , classical mechanics , optics , quantum mechanics , geometry , mathematics
The effect of rotational motion of linear molecules on their hyper‐Rayleigh scattering spectra is calculated from angular momentum theory. The expressions derived for the intensities of the hyper‐Raman rotational lines are used to calculate the rotational structure of the hyper‐Rayleigh line of gaseous CO.