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Zur Struktur des Mannans von Candida guilliermondii H
Author(s) -
Rademacher K. H.,
Reuter G.
Publication year - 1978
Publication title -
zeitschrift für allgemeine mikrobiologie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.58
H-Index - 54
eISSN - 1521-4028
pISSN - 0044-2208
DOI - 10.1002/jobm.19780180109
Subject(s) - mannose , mannan , chemistry , oligosaccharide , mass spectrometry , side chain , chromatography , stereochemistry , polysaccharide , biochemistry , organic chemistry , polymer
The mannan of Candida guilliermondii was acetolyzed and the seperation by gel chromatography gave five neutral fragments with the characteristic nuclear magnetic resonance spectra, mannose, mannobiose, mannotriose, mannotetraose, and mannopentaose. All oligosaccharide fragments were composed of mannose in α‐linkage. Methylation analysis combined with gas chromatography‐mass spectrometry demonstrated (1 → 6)‐linked d‐mannopyranose main chains with (1 → 2)‐linked d‐mannopyranose side chains.