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Snapshots of lignin oxidation and depolymerization in archaeological wood: an EGA‐MS study
Author(s) -
Tamburini Diego,
Łucejko Jeannette Jacqueline,
Ribechini Erika,
Colombini Maria Perla
Publication year - 2015
Publication title -
journal of mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 1076-5174
DOI - 10.1002/jms.3631
Subject(s) - lignin , depolymerization , chemistry , cellulose , pyrolysis , archaeology , pyrolysis–gas chromatography–mass spectrometry , degradation (telecommunications) , mass spectrometry , environmental chemistry , organic chemistry , geography , chromatography , telecommunications , computer science
Evolved gas analysis‐mass spectrometry (EGA‐MS) was used for the first time to study archaeological wood, in order to investigate its chemical degradation. The archaeological wood was from an oak pile from a stilt house found in the Neolithic ‘La Marmotta’ village (Lake Bracciano, Rome, Italy). The sampling was performed from the external to the internal part of the pile, following the annual growth rings in groups of five. In addition, sound oak wood and isolated wood components (holocellulose and cellulose) were also analyzed, and the results were used to highlight differences because of degradation. Our study demonstrated that EGA‐MS provides information on the thermo‐chemistry of archaeological wood along with in‐depth compositional data thanks to the use of MS. Our investigations not only highlighted wood degradation in terms of differences between carbohydrates and lignin content, but also showed that lignin oxidation and depolymerization took place in the archaeological wood. Mass spectral data revealed differences among the archaeological samples from the internal to the external part of the pile. An increase in the formation of wood pyrolysis products bearing a carbonyl group at the benzylic position and a decrease in the amount of lignin dimers were observed. These were related to oxidation and depolymerization reactions, respectively. Copyright © 2015 John Wiley & Sons, Ltd.