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Cluster emission and chemical reactions in oxygen and nitrogen ices induced by fast heavy‐ion impact
Author(s) -
Ponciano C. R.,
Martinez R.,
Farenzena L. S.,
Iza P.,
Homem M. G. P.,
Naves de Brito A.,
Wien K.,
da Silveira E. F.
Publication year - 2008
Publication title -
journal of mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 1076-5174
DOI - 10.1002/jms.1429
Subject(s) - sublimation (psychology) , chemistry , ion , cluster (spacecraft) , analytical chemistry (journal) , nitrogen , oxygen , mass spectrometry , mass spectrum , sputtering , yield (engineering) , atomic physics , thin film , nanotechnology , psychology , physics , organic chemistry , chromatography , computer science , psychotherapist , programming language , materials science , metallurgy
Two ices, O 2 and a mixture of O 2 and N 2 , are bombarded by 252 Cf fission fragments (FF) (∼65 MeV at target surface); the emitted positive and negative secondary ions are analyzed by time‐of‐flight mass spectrometry (TOF–SIMS). These studies shall enlighten sputtering from planetary and interstellar ices. Three temperature regions in the 28–42‐K range are analyzed: (1) before N 2 sublimation, in which hybrid chemical species are formed, (2) before O 2 sublimation, in which the TOF mass spectrum is dominated by low‐mass (O 2 ) p cluster ions and (3) after O 2 sublimation, in which (N 2 ) p or (O 2 ) p cluster ions are practically inexistent. In the first region, four hybrid ion series are observed: NO n −1 + , N 2 O n −2 ± , and N 4 O n −4 − . In the second region, two positive and negative ion series are identified: (O 2 ) p O ± and (O 2 ) p O 2 ± . Their yield distributions are fitted by the sum of two decreasing exponentials, whose decay constants are the same for all series. It is observed that the cluster ion desorption from solid oxygen is very similar to that of other frozen gases, but its yield distribution oscillates with a three‐ or six‐atom periodicity, suggesting O 3 or 3O 2 units in the cluster structure, respectively. Copyright © 2008 John Wiley & Sons, Ltd.