Investigations into the regioselective deuteriation of enolates derived from silyl enol ethers and enolacetates | Zendy

Coumbarides Gregory S. | Zendy; Eames Jason | Zendy; Weerasooriya Neluka | Zendy

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Investigations into the regioselective deuteriation of enolates derived from silyl enol ethers and enolacetates

Author(s) -

Coumbarides Gregory S.,

Eames Jason,

Weerasooriya Neluka

Publication year - 2001

Publication title -

journal of labelled compounds and radiopharmaceuticals

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.432

H-Index - 47

eISSN - 1099-1344

pISSN - 0362-4803

DOI - 10.1002/jlcr.519

Subject(s) - regioselectivity , chemistry , enol , silylation , lithium (medication) , silyl enol ether , enol ether , silyl ether , ether , similarity (geometry) , ketone , stereochemistry , medicinal chemistry , organic chemistry , catalysis , psychology , image (mathematics) , artificial intelligence , psychiatry , computer science

Results are reported on the regioselective C ‐deuteriation of a series of enolates derived from the addition of MeLi to the related enolacetate and silyl enol ether and discussed in terms of the similarity between these methods; comments are made on the possible role of the additive, lithium tert ‐butoxide. Copyright © 2001 John Wiley & Sons, Ltd.

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