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The synthesis of 14 C‐safrole, myristicin and elemicin labeled in the allyl side chain
Author(s) -
Walker M.,
McKinney J.,
Oswald E.
Publication year - 1974
Publication title -
journal of labelled compounds
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.432
H-Index - 47
eISSN - 1099-1344
pISSN - 0022-2135
DOI - 10.1002/jlcr.2590100306
Subject(s) - allylic rearrangement , side chain , methylene , safrole , chemistry , wittig reaction , chain (unit) , medicinal chemistry , organic chemistry , catalysis , physics , chromatography , astronomy , polymer
The preparation of 1‐[ (3′‐ 14 C)‐Allyl]‐3,4‐methylene dioxy‐,1‐[(3′‐ 14 C)‐allyl]‐3‐methoxy‐4,5‐methylene dioxy‐, and 1‐[(3′‐ 14 C)‐allyl]‐3,4,5‐trimethaoxy benzenes is described. The 14 C‐label was introduced into the 3′‐carbon of the allylic side chain via the Wittig reaction.